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 Healthy Baking: Gluten-Free

For great gluten-free recipes, visit: http://www.glutenfree.com/recipes.htm

The Celiac Disease & Gluten-Free Diet Support Page has provided information and support for people with celiac disease or gluten intolerance since 1995, including important gluten-free and wheat-free diet resources. The purpose of this site is to provide people who have celiac disease or gluten intolerance, and are not aware of it, with a means of figuring out what their problem is, and to help those who know they have it lead more comfortable and healthy lives.

For people following a gluten free diet, finding acceptable gluten-free baked goods can be extremely challenging. Why do gluten free breads and cakes often pale in comparison to their gluten-rich cousins? The answer lies in the way traditional baking methods make use of the properties of gluten. Once you understand these properties, you can begin to work around them and find or make acceptable alternatives.

"Gluten" is defined as the mixture of many protein fragments (called peptide chains or polypeptides) found in common cereal grains such as wheat, rye, barely and oats. Wheat is the only grain considered to contain true "gluten" and the peptides that predominate in wheat gluten are gliadin and glutenin. In baking terminology, "gluten" is defined as a network of intertwined water insoluble proteins (gliadin and glutenin) with water molecules trapped in between. The fibrous protein strands of glutenin and gliadin have properties of elasticity and plasticity that make raised breads possible. Rye flour contains gluten consisting of only glutenin and not gliadin, making it inferior to wheat gluten for baking. Other grains such as barley and oats have small amounts of gluten. This is why wheat flour is often added to rye and other non-wheat flours when making raised breads.

Gliadins and glutenins are both long molecules. Under a microscope, gliadins look like compact balls while glutenin molecules resemble fishing line that has been coiled or folded back upon itself. When mixed together, as they are in dough, these two proteins form a tangle of strands. Carbon dioxide gas from yeast and sourdough (as well as other leavening agents such as baking powder or baking soda used in quick breads and cakes) are trapped by the strands of gluten which must both expand and simultaneously contain the gas.

This is where elasticity and plasticity come into play. The gluten must be plastic enough to stretch with the gas but also elastic enough (think "memory yarn" from L'eggs pantyhose here) so as to hold its shape. Otherwise the gas would simply escape the dough and dissipate into the surrounding air. As the yeast dough is exposed to processing such as kneading or beating, the tangled strands of gluten begin to unfold into a more uniform mass and the dough becomes more stiff, smooth and shiny. Those who have ever attempted to bake bread will recognize this as the stage at which the recipe typically says, "knead dough until smooth and elastic."

Baking Gluten-Free: (Ingredient Sources)

The challenge in gluten free bread baking is finding a combination of flours and binders that can fulfill or at least approximate the functions of gluten. Fortunately, a wide variety of specialty flours are now available. These include rice flour, sweet rice flour, bean flour, tapioca flour, potato starch flour, potato flour, corn flour, popcorn flour, arrowroot flour and nut flours.

Additional specialty ingredients such as rice polish, corn starch, arrowroot starch, rice bran, xanthan gum, guar gum, and corn meal are all useful ingredients for gluten-free baking. Xanthan gum is a powder milled from the dried cell coat of a microorganism called "Xanthomonas campestris" grown in laboratory conditions. It works as a substitute for the gluten in yeast breads and other baking with gluten-free flours. Guar gum is a powder derived from the seed of the plant "Cyamopsis tetragonolobus." This gum can have a laxative effect and cause gastrointestinal distress in some individuals. These two gums are interchangeable in gluten-free bread recipes.

Here are several points to consider prior to baking your first loaf of gluten-free bread. Air temperature, humidity, the freshness of the yeast, and whether you are making the bread by hand or with a machine all affect the success of baking a gluten-free bread. Breads baked from straight rice flour are considered to be the most demanding and tricky. The bean flours and gluten-free flour blends tend to be more forgiving. The addition of xanthan gum or guar gum greatly improves the texture of breads. Finally, while traditional recipes discuss kneading time, gluten-free recipes stress beating the dough. The dough should look like thick cake batter if you are making it by hand; if you are using a machine, the dough should form a shiny mound, but not develop into a heavy ball.

Additional Pointers:

bulletTest any yeast that is nearing the expiration date by putting about 1 tablespoon into 1/2 cup of water with 1 teaspoon of sugar. If it doesn't foam up to double volume in 1 0 minutes, discard it and buy new yeast.
bulletTo eliminate measuring cup variation, use the same cup or style of cup for all measurements whether wet or dry.
bulletDifferent brands and grinds of rice flour may require a variation in the amount of water or liquid in a recipe.
bulletLemon juice or dough enhancer added to a recipe to balance the pH factor both enhances the flavor and acts as a preservative.
bulletCottage cheese and ricotta cheese can be interchanged in recipes, but the taste will be slightly different. Cubed tofu can substitute for the above cheeses, but decrease the liquid somewhat.
bulletOne teaspoon of unflavored gelatin added to the dry ingredients can add spring to the texture of your bread, but it is always optional.
bulletRemember always to bring ingredients (except water) to room temperature before starting to bake, thus avoiding cooling the yeast too much. Cold eggs can be warmed by putting in a pan of warm water for a couple of minutes.
bulletWhen experimenting with a recipe, change only one ingredient at a time.
bulletSugar or liquid sweetener: For machines, all the sugar can be added to the dry ingredients. Liquid sweetener (molasses, honey, etc.) should be added to the wet ingredients. If mixing by hand, reserve 1 teaspoon of sugar and add it to the water to make the yeast slurry. When converting a recipe from sugar to a liquid sweetener such as honey or molasses, cut down the amount of liquid (water) by the amount of sweetener added.
bulletMilk powders retain the sugar (lactose) of the milk, so when replacing the dry milk powder in a recipe with a nondairy substitute, add about 2 extra tablespoons sugar to the recipe.

References:

Alford, Jeffrey & Duguid, Naomi, " Flatbreads and Flavors; A Baker's Atlas," 1995, William and Morrow and Company, Inc.

Clayton, Bernard Jr.. "Bernard Clayton's New Complete Book of Breads," 1987, Simon & Schuster.

Hagman, Bette, "The Gluten-Free Gourmet Cooks Fast and Healthy," 1996, Henry Holt & Company, NY.

McGee, Harold, "On Food and Cooking: The Science and Lore of the Kitchen," 1984, MacMillen Publishing Company, NY.

Wittenberg, Margaret M., "Good Food: The Comprehensive Food and Nutrition Resource," 1995, The Crossing Press, CA.

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