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The Pantry: CHOCOLATE & COCOA
Chocolate, Cocoa & Carob Types

choc·o·late
Pronunciation: 'chä-k(&-)l&t
Function: noun
Etymology: Spanish, from Nahuatl chocolAtl
Date: 1604

Cacao fruit

Nineteenth century engraving of the cacao fruit.

1: a beverage made by mixing chocolate with water or milk
2: a food prepared from ground roasted cacao beans
3: a small candy with a center (as a fondant) and a chocolate coating
4: a brownish gray
- chocolate adjective
Scientific name: Theobroma Cacao (in Greek, theobroma means god food)

1 ounce baking chocolate EQUALS 1 square  

This is the usual measurement for grocery store bought baking chocolate. Check the package for measurements, just in case
The Chocolate Time Line:
bullet1824: John Cadbury, an English Quaker, begins roasting and grinding chocolate beans to sell in his tea and coffee shop. In 1842 Cadbury's Chocolate Company in England creates the first chocolate bar.
bullet1875: A Swiss chocolate maker, Daniel Peter, mixes Henri Nestle's condensed milk with chocolate and the two men found a company to manufacture the first milk chocolate.
bullet1894: Milton Hershey adds a line of chocolate to his caramel manufacturing business. Soon he invents the Hershey Bar by experimenting with milk chocolate. Hershey's Cocoa appears next.
bullet1896: Leonard Hershfield invents the Tootsie Roll, named after his daughter.
bullet1897: Brownies are first mentioned in print, listed for sale in the Sears, Roebuck and Co. catalogue.
bulletAbout 1900: A machine called the enrober is invented to replace the task of hand-dipping chocolate.
bulletHershey's Milk Chocolate Bar was invented in 1900.
bulletReese's Peanut Butter Cups was invented 1923.
bulletButterfinger was invented in 1923.
bulletSnickers Bar was invented in 1930.
bullet3 Musketeers Bar was invented in 1932.
bulletKit Kat was invented 1933.
bulletNestle's Crunch was invented 1938
bulletM&M's were invented in 1940.
There are about 30 milligrams of caffeine in your average chocolate bar, while a cup of coffee contains around 100 to 150 milligrams.
One of the most pleasant effects of eating chocolate is the "good feeling" that many people experience after indulging. Chocolate contains more than 300 known chemicals. Scientists have been working on isolating specific chemicals and chemical combinations which may explain some of the pleasurable effects of consuming chocolate. In the 1940s and 50s, Hershey extracted a stimulant called theobromine from its cocoa beans and sold it to Coca Cola, which used it to pep up its soda.
When cocoa beans are roasted and ground, they can be mixed with fat and other solids to create chocolate, or processed into dry cocoa powder. 
bullet Introduction
bullet What Comes From the Cocoa Bean & Chart 
bullet How Chocolate and Cocoa Powder are Made
bullet Detailed Information: Chocolate, Cocoa & Carob Types
bullet Chocolate Terms
bullet Chocolate Confections 101
bullet Chocolate & Cocoa Substitutes
bullet Chop
bullet Decorating with Chocolate
bullet Dip & Mold
bullet Melt 
bullet Make Ganache
bullet Seize
bullet Store
bullet Temper
bullet Terms
bullet Is Chocolate Good for You ?

Nationally available baking chocolate brands: High quality chocolate can found at specialty food stores, but good ones for baking are usually found in the grocery store. Be sure to check the recipe before setting out to buy the chocolate for it - if you use the wrong type of chocolate, all your efforts may be wasted; certainly the results may be different. Within the following categories, you may use the brands we name interchangeably with only subtle differences in taste and/or texture. (Chocolatier Magazine)

Unsweetened chocolate: Baker's, Ghirardelli, Hershey's or Nestlé

Swiss dark chocolate/bittersweet chocolate: Baker's, Scharffren Berger

Semisweet chocolate: Ghirardelli, Hershey's, Nestlé or Baker's

Semisweet chocolate chips: Ghirardelli, Hershey's, Nestlé or Baker's

Sweet chocolate: Baker's German Sweet Chocolate or Ghirardelli Sweet Dark Chocolate

Swiss milk chocolate: Lindt Swiss Milk Chocolate

Milk chocolate chips: Baker's, Hershey's or Nestlé

White chocolate: Callebaut White Superior has a nice "middle-of-the-road" flavor and gets my vote. Ghirardelli is less expensive and just as good. Look for a bar that contains cocoa butter and it off white, then you will have a better quality product. 

White chocolate chips: Hershey's

Couverture/coating chocolate: Cacao Barry, Carma, Ghirardelli, Lindt or Valrhôna.

Unsweetened non-alkalized cocoa powder: Hershey's, Ghirardelli or Nestlé

Unsweetened alkalized cocoa powder (Dutch processed or European style): Droste or Fry's.

Pure chocolate usually comes in blocks, with smaller quantities in 1-ounce wrapped bars. But, you can also purchase pure chocolate wafers -- they look like large chocolate chips -- and you don't have to chop them. They are available at any outlet that sells good, pure  chocolate. Don't confuse them with courverture or compound chocolate. 

Good brands for high quality pure chocolate are Valrhona, Lindt, Callebaut, Tobler, and Scharffren Berger, an American brand. I like to use Valrhona for enrobing and Callebaut for ganache but, find a chocolate you like and stick with it.

Chocolate has been called the food of the Gods.

Chocolate comes from Cocoa beans.

Americans don't win the prize for highest world wide chocolate consumption. The Swiss, whose per capita consumption is a whopping 19 pounds per person a year, wins. Following are Norway, the United Kingdom, Belgium / Luxembourg, the Netherlands, Germany, Austria, Ireland, Denmark, Sweden -- and then the U.S.A., at 9 pounds per person a year.

ABOUT CHOCOLATE & COCOA POWDER: There is specialty, pure chocolate, generally found in gourmet shops and baking chocolate, found in the grocery store. Pure chocolate can be melted to liquid form, poured into molds to cool, sculpted with and become confections of any shape desired. Baking chocolate is perfect to use in a recipe. Chocolate can be pressed into cocoa powder and used for baking, making ice cream and sorbets. Chocolate chips or chunks can be added to a batter before baking, creating a recipe studded with chocolate throughout. 

For best results, be sure to use the type of chocolate and cocoa powder that the recipe calls for, as different varieties will react differently to heat and moisture, plus the taste and texture can change. But, you can substitute one for another if you are aware of how to do it. (Chocolate & Cocoa Substitution Tips)Happy Baking, Sarah

CHOCOLATE AND COCOA POWDER FROM THE COCOA BEANS AND OTHERS : There are three main types of ingredients produced from the cocoa bean: butter, powder, and extracts. (For more detailed information about each type, click here).

VARIETY DESCRIPTION FLAVOR USE
CHOCOLATE LIQUOR Made by grinding the center of the cocoa bean (nib) to a liquid form. Contains about half cocoa butter and half cocoa solids when bean is pulverized. Bitter Baking ingredient
COCOA SOLIDS Responsible for the dark, strong flavor Strong Chocolate ingredient
COCOA BUTTER The vegetable fat from the cacao been extracted from chocolate liquor Creamy Baking ingredient
BAKING, BITTER Non-alcoholic unsweetened chocolate liquor in solid form Bitter Baking ingredient
COCOA POWDER (NATURAL) Powdery remains of chocolate liquor after cocoa butter is removed Ranges from mild to strong, unsweetened Baking, reduced fat and calorie recipes, ice cream flavoring
COCOA POWDER (DUTCH PROCESSED)  Cocoa powder treated with mild alkalizing agent such as baking soda Stronger flavor and darker color than cocoa powder To create deep color in baked goods, ice cream, beverages
DARK, SEMI-SWEET, BITTER-SWEET CHOCOLATE The darkest of eating chocolates, high chocolate liquor content with added sweeteners Strong chocolate flavor with minimal dairy flavor Chocolate chips, baking, coatings
MILK CHOCOLATE Contains cocoa butter, milk, sweeteners & flavorings that are added to chocolate liquor Creamy, mellow chocolate with strong milk taste Candy bars, baking, coatings
CHOCOLATE (CONFECTIONERY) FLAVORED COATING Used as coating for candies. Contains sugar, milk powder, hardened vegetable oil & flavorings. It does not contain cocoa butter   Similar to other natural chocolate but may have a waxy taste Less expensive alternative to natural chocolates
WHITE CHOCOLATE: is not considered chocolate because it does not contain cocoa solids. Blend of cocoa butter, milk solids, sugar, flavorings, such as vanilla and contains no chocolate solids Sweet, dairy taste with hint of chocolate from the cocoa butter Candy bars, baking, coatings
CAROB: The carob bean is from an eastern Mediterranean evergreen tree of the pea family. It is not chocolate. Made from the carob bean, it is sometimes used by those who are allergic to chocolate  Available as either toasted or untoasted powder (toasting helps bring out the flavor)  Carob powder, raw pods and carob chips

adapted from cnn.com

Did you know?...Experts who make chocolates are also known as 'chocolatiers'. Chocolate lovers are called 'chocoholics'.

HOW CHOCOLATE & COCOA POWDER ARE MADE: To make chocolate and cocoa powder, processors ferment and then roast the cocoa bean, the fruit (or pod) of the tropical tree, Theobroma cocao, cultivated in tropical climates within 10 to 20 degrees north and south of the Equator and on the Big Island of Hawaii. Like coffee, cocoa does not acquire the richness of its color and the fullness of its flavor until it is roasted. Beans that are going to be used for cocoa powder are roasted longer than those for chocolate because chocolate goes through other processes after roasting that develop flavor.

There are three basic things that must be done by the chocolate maker to make a chocolate bar:
bulletAdding ingredients - The chocolate that we eat contains sugar, other flavors (like vanilla) and often milk (in milk chocolate). The chocolate maker adds these ingredients according to his or her secret recipe.
bulletConching - A special machine is used to massage the chocolate in order to blend the ingredients together and smooth it out. Conching can take as long as three days in the finest chocolates. Raw unprocessed chocolate is gritty, grainy and really not suitable for eating. Swiss chocolate manufacturer Rudolph Lindt discovered a process of rolling and kneading chocolate that gives it the smoother and richer quality that eating chocolate is known for today. The name 'conching' comes from the shell-like shape of the rollers used. The longer chocolate (and any ingredients added like milk, vanilla, extra cocoa butter) is conched, the more luxurious it will feel on your tongue.
bullet Tempering - is a carefully controlled heating process. It is a process where the chocolate is slowly heated, then slowly cooled. 

Once roasted, the beans are cracked and winnowed to expose the cocoa nib, or core. Cracking breaks the nib free of the shell and reduces it to small pieces, allowing the winnowing to blow away the hulls with powerful fans. Sometimes, the nibs are first blended with other chocolate nib varieties of different and type to produce the unique and complex "chocolate recipe" that is the characteristic of each chocolate manufacturer's particular "flavor". 

European chocolate tends to be creamier and with more flavor than American. It's because European chocolate manufacturers roast the beans at a lower temperature for a longer period of time, which develops their flavor. On the other hand, most American manufacturers roast their beans at higher temperatures for shorter periods of time. The flavor becomes rougher, requiring more added sugar to compensate. However, this has changed recently with Schaffran Berger, an American brand with European taste and texture.

The chocolate nibs are then crushed and ground while hot from roasting by large stone mills into a thick rich-looking "liquor" or "mass" called chocolate liquor, also known as the essence of chocolate.

 Chocolate liquor is nonalcoholic, despite its name, containing two components, cocoa solids (50 % to 58 %) and cocoa butter (42 % to 50 %). Cocoa solids are what give it its marvelous and distinct chocolaty flavor and dark color, and cocoa butter contains the fat which is what gives it its smooth, creamy richness. 

Different types of chocolate: If the bitter chocolate liquor is molded and solidified after the nibs are crushed, ground and tempered, it is called "baking" or dark "unsweetened" chocolate. These are referred to as "pure chocolates". All chocolate types besides "baking" or dark "unsweetened" chocolate are not considered to be "pure" chocolate. In general, the darker the chocolate, the more chocolate liquor it contains -- from 100% in unsweetened chocolate to 10% for milk chocolate. The darkest chocolate will provide the most chocolate flavor. 

COCOA BEANS: There are three major varieties of cocoa beans: forastero, criollo, and trinitario. Both the Criollo and Trinitario varieties are considered to have a better flavor than the Forastero. Thus criollo is blended with forastero to improve the flavor.
bulletForastero accounts for more than 90% of the world's usage. It is produced primarily in the West African countries of Ghana, Nigeria, Cameroon, and the Ivory Coast.
bulletCridlo is produced in Venezuela and Central America as well as Papua New Guinea, Java, and Samoa.
bulletTrinitario is believed to be a hybrid of the other two varieties and is produced in Venezuela, Trinidad, Sri Lanka as well as other countries. It is used in the manufacture of certain high quality eating chocolates.

If not, the crushed nibs continue on in the chocolate-making process and other types of chocolate are made. It's the addition and proportion of ingredients to one another that distinguish one brand of chocolate from another. The proportions of the ingredients for each type of chocolate is regulated by the U.S. Food and Drug Administration (USDA).

Chocolate's Basic Ingredients: Cocoa paste, cocoa butter, sugar and optionally milk (powdered or condensed) are the four basic ingredients for making an entire range of semi-sweet or bittersweet chocolates. Flavorings (usually vanilla) are also added.

Plain chocolate: cocoa paste + cocoa butter + sugar
Milk chocolate: cocoa paste + cocoa butter + sugar + milk
White chocolate: cocoa butter + sugar + milk

Another type of chocolate is gianduia. It is a blend of chocolate and roasted hazelnuts. The result is a homogeneous, paste-like mixture which is already pleasant to taste, but still feels gritty to the palate. .  

After the ingredients for making a certain type of chocolate have been carefully weighed out in accordance with the recipe, they go into a mixer where rotating, kneading arms thoroughly mix all the ingredients. Chocolate is mixed with small amounts of lecithin. This helps it mix more easily and makes the chocolate smoother. The finished mixture again goes through rolling machinery which pulverizes the tiny particles of cocoa and sugar even further to give the chocolate its smooth, eating texture.

Conching got its name from the similarity of the early machines to the shape of the seashell. During the conching process, which can take up to 72 hours for a high quality chocolate, the mixture is constantly aerated by stirring to release volatile and off-flavors. Gradually, the bitter taste disappears and the flavor of the chocolate becomes fully developed. Tempering, molding, and hardening remain the final steps before packaging.  

The paste is transported to conching machines which heat and stir the paste in the last and most important refining process. As the paste is stirred, cocoa butter is added which makes the chocolate ready for molding. As the chocolate turns over in the conching machine, a kind of aeration of the liquid chocolate paste then takes place: its bitter taste gradually disappears and the flavor is fully developed. The chocolate no longer seems sandy, but dissolves meltingly on the tongue. 

High quality chocolate is conched for several days and lower quality chocolate are conched for only a few hours.

The still-warm conched chocolate is placed in a tempering machine. This is the process that gradually raises then lowers and raises the temperature to a set degrees. The tempering prevents separation in the chocolate when it's filled into bar molds and hardens. Proper tempering also results in a silky sheen and crisp "snap" when broken - another sign of a superior quality chocolate bar.

The quality of chocolate (and its price) is determined by its cocoa butter content. By processes called "rolling" and "conching" the chocolate develops a high degree of flavor and smoothness that further refines these "eating" chocolates. 

Chocolate as a Thickener: Did you know that ounce-for-ounce, unsweetened chocolate has more thickening power than bittersweet? Cocoa solids are rich in starches, with unsweetened having the more. 

When I used unsweetened chocolate in a Ganache filling recipe, it was significantly stiffer and also had a viscous, gummy quality. On the other hand, when made only with bittersweet chocolate, it had a pleasantly smooth and creamy texture.

Comparable amounts of bittersweet or semisweet chocolate and unsweetened chocolate plus sugar will not produce identical recipes. While a direct swap might work well enough in fudgy brownies, it could wreak havoc on a delicate custard or filling.

The higher the cocoa butter content, such as in Callebaut, the better the chocolate and higher quality the finished confection will be. Read the chocolate's label and it should read: "% cocoa butter". For instance, Callebaut Dark Semi sweet Chocolate CA-D811NV-25 is a dark couverture chocolate, that is bittersweet and has 51.5% cocoa butter. Callebaut Milk Chocolate CA-C823NV-25 contains 31.5% cocoa butter. Cocoa butter is also one of the ingredients of white chocolate. However, the high cost of cocoa butter has prompted some manufacturers to replace it with a proportion of vegetable fat, labeled as such

Cocoa powder is made by taking chocolate liquor and pumping it into special hydraulic presses that extract cocoa butter and drain it off. The remaining compacted cocoa solids are released from the press in the form of a hard cake, which is then broken up and ground to become cocoa powder, called Natural Cocoa Powder. Cocoa powder still retains some of the cocoa butter after pressing. Low fat cocoa, the most commonly used, has 10% to 12% fat, medium fat cocoa retains 14% to 16%, and high fat cocoa, sometimes called "breakfast cocoa", has a fat content of 22% to 24%. For many applications, cocoa powder is "Dutch processed", to reduce its natural acidity, and to enhance its color and flavor.

The cocoa powder can be treated with alkali either after roasting and after grinding. The alkali darkens its color, softens its flavor and makes it able to be easily dispersed in liquid over nonalkalized powder. If left untreated with alkali, the chocolate liquor is processed into natural cocoa powder.

Key factors to be aware of when tasting chocolate and chocolate confections: These key factors, such as appearance, aroma, snap, texture, mouthfeel, flavor and aftertaste are universally recognized. Chocolate is tested when it is the cooler side of room temperature, for it tastes and looks best when it is.

To determine the "best" dark chocolate, use the following criteria:

bullet

Appearance: Chocolate should be lustrous and evenly colored, with no gray streaks or dots. Dullness and signs of bloom indicate that it has not been handled properly.

bullet

Aroma: Chocolate should smell rich and flavorful, not burned or harsh. The aroma is primarily chocolate and the fillings used should not overpower it.

bullet

Snap: Chocolate should break firmly and cleanly, not crumble or splinter. 

bullet

Texture / Mouthfeel: The chocolate should be smooth and creamy, not greasy. It should melt in your mouth. When consumed, it should be described as: smooth, velvety, and creamy.

bullet

Flavor:  The flavor should be harmonious, well-balanced, not too bitter or too sweet. Other flavors added should be harmonious and not overpower it. 

bullet

Aftertaste: The flavor should linger in your mouth pleasantly, without a bitter or burnt aftertaste.

To determine the "best" milk chocolate, use the following criteria:

bulletAppearance--Fine chocolate should be rich in color, with a smooth, glossy surface. Cracked or dull-colored chocolate is an indication of poor quality.
bulletSnap--High quality chocolate should have a decisive "snap" when it is broken.
bulletAroma--A strong chocolaty aroma - not one that's fruity or flowery - indicates good chocolate.
bulletMouthfeel--Fine milk chocolate should feel creamy and melt smoothly across the palate. The extra fine creamy texture is achieved by conching (agitation/blending) ingredients. The longer the conching, the creamier the chocolate.
bulletTaste--The taste of high quality milk chocolate should be rich, sweet and chocolaty - never harsh or bitter.

Some information from Peters Chocolate, division of Nestle.

STORING CHOCOLATE:

Well-wrapped, chocolate is best kept at around 68 - 72 degrees Fahrenheit, the temperature of a nice pantry or dark cabinet, away from strong odors. Kept at this temperature, chocolate (assuming it isn't covering fruit or other perishables) has a shelf life of about a year. When you freeze chocolate and then thaw it out, it will have a greater tendency to bloom. But, I keep my chocolate frozen all the time.

If chocolate is or improperly tempered, a "bloom" will occur. This is when the cocoa butter separates from the solids. You can see the bloom because it appears as a colored film on the outside of the chocolate. It is harmless and will disappear as soon as it is melted. 

If chocolate BLOOMS, a colored film appears on the outside.

FILM COLOR

CAUSE 

Gray

Improper tempering

Milky (fatbloom)

Melted & resolidified during storage

Yellow color  (sugarbloom)

Caused by condensation

Fatbloom - When a thin layer of fat crystals forms on the surface of the chocolate. This will cause the chocolate to lose its gloss and a soft white layer will appear, giving the finished article an unappetizing look. Fatbloom is caused by the recrystallization of the fats and/or a migration of a filling fat to the chocolate layer. Storage at a constant temperature will delay the appearance of it.

Sugarbloom - This is a rough and irregular layer on top of the chocolate. Sugarbloom is caused by condensation (when the chocolate is taken out of the refrigerator). This moisture will dissolve the sugar in the chocolate. When the water evaporates afterwards, the sugar recrystallizes into rough, irregular crystals on the surface. This gives the chocolate an unpleasant look. You can prevent sugarbloom by preventing temperature shocks. When chocolate comes out of a cold room, it should be stored in a warm area long enough before opening the package to keep direct condensation from forming.

Chocolate is sensitive to heat, changes in temperature, and also picks up flavors from other foods, so wrap it well in foil and then again in plastic wrap.  Go to Pantry, Ingredient Storage

Recent studies have shown that eating chocolate can be beneficial to your health. Chocolate contains a substance called catechins that could help prevent cancer and heart disease.

Q: Can I give chocolate to my dog? A: Unequivocally, NO! The theobromine in chocolate that stimulates the cardiac and nervous systems is too much for dogs, especially smaller pups. A chocolate bar is poisonous to dogs and can even be lethal. The same holds true for cats, and other household pets.

Catechins are strong antioxidants which clear away destructive molecules in the body called free radicals. Free radicals damage cells which help trigger heart disease and cancer. A large amount of antioxidants in your diet can help reduce your risk for developing heart disease and cancer.

Cocoa powder and chocolate are good sources of antioxidants.  Dark chocolate contains significantly higher amounts than milk chocolate per serving. You can also find catechins in large doses in green tea.

In addition, researchers have discovered that physical and emotional enjoyment from eating chocolate, even in small doses, can enhance immune function for hours afterwards. They believe that life's small pleasures may have a cumulative effect in boosting the immune system over a long period.

The good news is that moderate chocolate consumption offers health benefits. The bad news is that you can't eat whatever you want because too much chocolate can lead to weight gain.

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